Liquor recommendations?

So typically I would only drink beer but I bought a jar of moonshine off a coworker who is about to move away (hence why I don’t just buy more from him). This moonshine was peach flavored and made by some guy in Kentucky off of limestone water 110 proof and incredibly smooth. Hot or maybe warm but absolutely zero bite whatsoever with a great subtle flavor. I didn’t know liquor could actually even be that good. Do you guys have any recommendations that might be up that same ally? Something smooth good flavor not punch you in the face that I could drink neat?