Vodka vs Wine (Potato Vodka specifically)

Chopin or other potato vodkas..

Riddle me this. Why does an espresso martini or vodka hot cocoa (I need anything warm as it’s FREEZING in the PNW where I am on vacation…) leave me relaxed but not drunk and I wake up the next morning feeling 10/10 BUT… two solid glasses of expensive french wine and I feel dizzy tipsy and wake up with that morning-after-ick feeling. Bloated. Tired. Literally, sometimes the spins from a few glasses of wine!

I would think it would be the opposite. Is it the potato vodka the key? Aside from the fact it is so smooth in an espresso martini and literally needs nothing aside from fresh brewed espresso and the Chopin. I recall having Tito’s in the past and it wasn’t nearly as good as Chopin, in my very novice opinion.

If relevant, I’m 43 and female so IYKYK.

PS I am tempted to try Luksuksowa but fear it wouldn’t treat me as well as Chopin.

Would welcome any feedback on whether it’s safe to have an edible after I’ve had an espresso martini as well.